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Curriculum Vitae Name Rai-Shung Liu (劉 瑞 雄) Birth Taiwan, roc, 1954, 10, 27


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Curriculum Vitae

Name Rai-Shung Liu (劉 瑞 雄)

Birth Taiwan, ROC, 1954, 10, 27.

Education B. Sc. National Tsing-Hua University, 1976

Ph. D. Columbia University, 1981.

Postdoctor, Texas A&M, 1981-1982

Professional Appointment:

Associate Professor, National Tsing Hua University 1982-1987.

Professor, National Tsing Hua University, 1987-present

Professional Activities and Honors:

(1) Recipient of outstanding research award, National Science

Council, (Taiwan), 1989-1995.

(2) Fellow of National Science Council, 1995-2001.

(3) Award from Chinese Culture and Academic Foundation, 1993

(4) Award for Research Fellowship from Foundation for the Advancement

of Outstanding Research Foundation. (1999-2003)

(5) Member of Advisory Board for Organometallics 1993-1995, 2011-1013.

(Chief Editor, Professor Dietmar Seyferth)

(6) Scholar Award for Natural Science from Education Ministry 2000.

(7) Recipient of National Chair Professorship from Education Ministry (2001-2004).

(8) Chair Professor of Natural Science, Tsing-Hua University (since 2003).

(9) Recipient of National Chair Professorship from Education Ministry with permanent honor (2005-2008)

(10) Member of Advisory Board for Synlett and Synthesis 2009-1011 (Thieme publisher (Chief Editor, Professor Peter Vollahardt)

Invited or Plenary Lectures on International Conferences (over 30 minutes)

(1) First International Conferences on Organic and Inorganic

Synthese, Taipei, Taiwan, 1991. (Invited lecture)

(2) Second International Conferences on Organic and Inorganic

Synthese, Taipei, Taiwan, 1992. (Invited lecture)

(3) International Conferences on Inorganic and Organometallic

Chemistry, 1995, Taipei, Taiwan (Plenary lecture)

(4) International Conferences on Organic Syntheses, Tohoku

University, Sendai, Japan (Invited Lecture)- April 7-8, 1996

(5) Workshop on Organometallic Chemistry Toward Organic

Syntheses, 1996, April 4-5, Kyoto University, Kyoto, 1996

(6) Taiwan-France Symposium on Organic Chemistry, December 19-21, 1996, Strasburg, France

(7) Workshop on Organometallic Chemistry, National Taiwan University, Taipei, Taiwan, (invited lecture) April, 23-24, -1997

(8) The 9th IUPAC Conference on “Transitional-metal Toward Organic Syntheses (OMCOS IX, IUPAC), Gottingen, 1997, July, 20-25 (Invited Lecture)

(9) 16th International conferences on Heterocyclic Chemistry, August 10-

15, 1997, Bozeman (Invited Lecture).

(10) Third International Conferences on Organic and Inorganic

Synthesis, Taipei, Taiwan, December 17-20, 1997. (Invited lecture)

(11) International Conference on Organic Synthesis-13th, Nazaki Conference-1998, Hokaido University, Sapporo, Japan June 14-15. (invited Lecture)-

(12) International Conferences on Taiwan-Japan Organic Syntheses, Hsinchu, Taiwan, (Plenary Lecture)- 1998, November 14-16

(13) International Symposium on the second SANKEN international symposium: chemical and physical Perspective for Molecular Devices, Osaka University, Osaka (Invited Lecture)-1999, January 26-27.

(14) International Conferences on Taiwan-US Organometallic Chemistry, Taipei, Taiwan, 1999, April, 6-8 (invited lecture)

(15) International Symposium on Taiwan and Belgium Organic Chemistry, Universite catholique de Louvain, Belgium, 1999, November 15-17 (invited speaker)

(16) The IUPAC XIXth International Conference on Organometallic Chemistry (XIX ICOMC), Shanghai, China (July 23-28, 2000), invited speaker.

(17) The Third International Conference for Chinese Inorganic Chemistry, Taipei, Taiwan (August 2-4, 2000), plenary lecturer.

(18) 2000 Pacific Chemical Conference on “New strategy for transition metal-catalyzed or mediated reactions” December 13-19, 2000. Hawaiian, Honolulu Invited Speaker (40 mins).

(19) The 18th International Congress of Heterocyclic Chemistry, July, 29-August 3, 2001, Yokohama, Japan. (35 minutes-invited speaker).

(20) Organic Chemistry in the 21th Century, Tetrahedron Symposium, April, 25-27, 2002, Shanghai, China (30 minutes, invited speaker).

(21) International Conference on Organic Chemistry, June 27-29, 2002, KAIST, Korea, Invited Speaker.

(22) The 16th IUPAC Conference on Physical Organic Chemistry, August 4th-9th, 2002, San Diego, USA, invited Speaker (30 minutes).

(23) International Conference on Organic Synthesis, March 1-3, 2004, Sanken, Osaka, University, invited lecture (40 mins).

(24) The 8th-International Conference on Chinese Organic Chemistry, Hong-Kong, Dec. 19-22, 2004, Plenary Lectures (60 mins).

(25) The International Conferences on Taiwan-Swiss Organic Syntheses, Taipei, Taiwan, March 3-4, 2005, invited lecture. (60 mins).

(26) 0th International Conference on Cutting-Edge Organic Chemistry in Asia,

Nagoya University, March 8-12, 2006, Japan, invited speaker (30 mins).

(27) the 11th International Symposium on Organic Reactions, Kobe, 2006, April 24-26, 2006, invited speaker (20 min).
(28) The First International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Procticability, Otsu, Japan, May 29-30th 2006, invited speaker. (35 min)

(29) The 75th Gorden Conference, Organic Reactions and Processes, Bryant University, July 16-21, 2006. (invited speaker, 25 min)

(30) The Taiwan-Indian International Conference, November, 25-26, 2007 (invited speaker, 30 min).

(31) The 5th Asian-European Symposium in catalysis, May 25-28, 2008, Obernai, France, invited speaker. (30 min).

(32) The 15th National Conference of Organometallic Chemistry, Nanjing, October, 20-23, 2008, invited speaker (plenary speaker).

(33) The 6th International Conference of Coordination Chemistry, Hong Kong, July 6-9, 2009, plenary speaker (50 min)

(34) The 5th International Conference of Gold Science, Heidelberg, July 25-29. 2009, invited speaker. (25 min).

(35) The 4th International Conference on Cutting-Edge Organic Chemistry in Asia, Bongkok, Thailand, Nov. 29-Dec 3, 2009, plenary speaker, (40 min).

(36) The 24th Internal Conference of Organometallic Chemistry, Taipei, July 18-24, 2010, invited speaker.

(37) The 11th-International Conference on Chinese Organic Chemistry, Taipei, October. 22-24, 2010, Plenary Lectures (40 mins).

(38) Pacifichem 2010, Hawaii, December 16-24, 2010. Transition-metal catalysis: efficiency and molecular complexity.

(39) IUPAC-sponsored OMCOS 16, 2011, Shanghai, China, plenary speaker.

(40) The 6th International Conference on Cutting-Edge Organic Chemistry in Asia, Hongkong, December 12-15, 2011, invited speaker.

(41) The first International Conference on Organometallics and catalysis, Beijin, China, November 18-21., invited speaker.

(42) 2012-Roken symposium on Organometallic Chemistry, November 30-31, Riken, Waco, Japan.

Research Interest

(1) Transition-metal organic chemistry,

(2) Organometallics in organic synthesis



(3) Synthesis of oxygen heterocycles via metal complexes
Publications: 215 scientific articles and five invited review papers


List of Publications (1989-2012)
23. Preparation and properties of molybdenum-pentadienyl complexes. A facile 3->5 reversible interversion for a pentadienyl ligand. G-H. Lee, S.-M Peng, I-C. Tsung and R.-S. Liu, Organometallics, (1989) 8, 2248.
24. Synthesis, characterization and structure of Iron-methyl-2-butenoate compounds. Ming-Huei Cheng, Yuh-Jiuan Wu and R. S. Liu, J. Organomet. Chem. (1989), 373, 119.
25. Transition-metal pentadienyl chemistry. Proceeding of the NSC-part A, R. S. Liu (1989), 13, 368.
26. Synthesis, characterization and structure of dicarbonyl(5-indenyl)3-pentadienyl molybdenum and its phosphine derivatives, Shie-Ming Peng, Gene-Hsian Lee, Fu-Shen Liu and Rai-Shung Liu., J Organomet. Chem. (1989) 377, 123-132.
27. Synthesis, characterization and reaction chemistry of complexes of the molybdenum-pentadienyl-nitrogen system, Shie-Fu Lush, Shin-Hwan Wang, Gene-Hsian Lee, Shie-Ming Peng, Suei-Lein Wang, Rai-Shung Liu, Organometallics, 1990, 9, 1862.
28. Synthesis, characterization and nucleophilic substitution-addition Reactions of manganese-oxapentadienyl compounds. Structural characterization of (5-CH2CHCHCOCH3)Mn(CO)2L. Organometallics, 1990, 9 , 1853.
29. Synthesis, characterization and structure of tungsten-pentadienyl compounds. An observable 5-3 equilibrium for a pentadienyl ligand. Sheng Liang Wu, Chih-Yi Cheng, Sue-Lein Wang and Rai-Shung Liu, Inorg. Chem. (1991) 30, 312.
30. Stereochemical aspects of the reactions on the CpMo(CO)2(syn-3-C3H4COCH3). Wong-Jung Vong, Shie-Ming Peng, Rai-Shung Liu, Organometallics, (1990), 9, 2187.
31. Stereocontrolled functionalization of molybdenum allyl complexes. A new approach to the stereoselective synthesis of 1,3-diols, Wen-Jung Vong, Shie-Ming Peng, Rai-Shung Liu, Gene-Hsian Lee and Rai-Shung Liu. J. Chem. Soc. Chem. Commun.., (1990), 1285.
32. Generation and aldol reaction of enolate anion adjacent to a CpMo(CO)2 fragment. A new approach to the stereoselective synthesis of 1,3,5-triols and 2-vinyl tetrahydrofuran, Shie-Shiung Lin, Wen- Jung Vong, Chih-Yi Cheng, Sue-Lein Wang Rai-Shung Liu, Tetrahydron Lett. (1990) 31, 7645.
33. Regio- and stereocontrolled functionalization of molybdenum allyl complexes. Wen-Jong Vong, Shie-Ming Peng, Shie-Shiung Lin, Wen-Jye Lin, and Rai-Shung Liu., J. Am. Chem. Soc. (1991) 113. 573-582.
34. Reaction chemistry in the condensation of amines with molybdenum -bound ketones and aldehydes. Gene-Ming Yang, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, Organometallics, (1991), 10, 1305-1310.
35. A novel intramolecular insertion of a metal-acyl group into a organic ketone. Gene-Ming Yang, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu,. J. Chem. Soc. Chem. Comm. (1991), 478.
36. Synthesis, characterization and Reactivity of (5-C5H7)V(CO) and its phosphine derivatives. Wen-Jye Lin, Gene-Hsian Lin, Shie-Ming Peng and Rai-Shung Liu, Organometallics, (1991) 10, 2519.
37. Control of nucleophilic regiochemistry by the diene conformation: Development of Synthetic Application for unstable 2-carboxylated-1,3-dienes, Ming-Huei Cheng, Yuung-Hsing Ho, Gene-Hsian Lee , Shie-Ming Peng and Rai-Shung Liu, J. Chem. Soc. Chem. Commun. (1991) 697 .
38. Formation of a carbon-carbon bond mediated by molybdenum in the intermediate 4-s-trans diene cation. Shie-Hsiung Lin, yuan-Jing Yang and Rai-Shung Liu, J. Chem. Soc. Chem. Commun., (1991) 1004.
39. A novel pathway of molybdenum-mediated cyclization reaction., Gene-Ming Yang, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu., Organometallics, (1991). 10, 2531
40. Reaction chemistry of metal-1-vinylpropargyl ligands with unsaturated Fe(O), Ru(O) and Os(O) Carbonyl Clusters., Ming-Huei Cheng, Gene-Hsian Lee, Shie-Ming Peng, and Rai-Shung Liu, Organometallics (1991), 10, 3600.
41. Formation of molybdenum-4-trimethylenemethane cation through carbon-carbon bond formation., Gin-Ming Su, Gene-Hsin Lee, Shie-Ming Peng and Rai-Shung Liu, J. Chem. Soc. Chem. Commun., (1992) 215.
42. Stereo- and regiocontrolled carbon-carbon bond formation mediated by tungsten in the s-trans-4-diene cationic intermediates, Ming-Huei Cheng, Yuun-Hsing Ho, Sue-Lein Wang, Shie-Ming Peng and Rai-Shung Liu, J. Chem. Soc. Chem. Commun., (1992) 45.
43. Molybdenum-mediated synthesis of isoxazole compounds through a nitrosyl insertion into a p-allyl ligand, Shie-Hsiung Lin, Shie-Ming Peng and Rai-Shung Liu. J. Chem. Soc. Chem. Commun., (1992) 616
44. Tungsten-Mediated Synthesis, Skeletal Rearrangement and Synthetic Applications of 1-2,5,-dihydro-3-furanyl rings. Ming-Huei Cheng, Gene-Ming Yang , Jin-Feng Chow, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, J. Chem. Soc. Chem. Commun. (1992) , 934.
45. The Reaction Chemistry between CpMo(CO)2(3-2-vinylallyl) and Electrophiles- A New Carbon-Carbon Bond Formation through molybdenum 4-trimethylenemethane cationic intermediates. Gene-Ming Yang, Gin-Ming Su and Rai-Shung Liu, Organometallics (1992) 11, 3444..
46. Reactions of Functionalized Metal-1-Propargyl Compounds with Unsaturated Cobalt and iron Carbonyl Clusters. Ming-Huei Cheng, Hsin-Guo Shu, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, Organometallics, (1993), 12, 108..
47. Molybdenum--allyl compounds for chemoselective synthesis of tetrahydrofurans, cis-1, 3-dienes cis-hexatrienes and isoxazoles compounds. Shie-Hsiung Lin, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, Organometallics (1993) 12, 2591.

48. An Unusual Transition-Metal-Mediated [2+2+2] Cyclization of Functionalized Alkenes. Ming-Huei Cheng, Shie-Hsiung Lin, Jin-Feng Chow, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, J. Chem. Soc. Chem. Commun.,(1993) 757.


49. Electrophilic Carbon-Carbon Bond-Forming Reaction of Molybdenum-3-Cyclohexadienyl Complexes. Shin-Hwan Wang, Yuan-Chi Cheng, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu. Organometallics (1993) 12, 3282.
50. -Face Differentiation in Michael Reaction to the Enone Group Adjacent to the CpMo(CO)2(p-allyl) Fragment: A New Approach to the Stereoselective Synthesis of 2,3,4,5-Tetrasubstituted Tetrahydrofuran Compounds. Lin, S.- H, Cheng, W.-J. , Liao, Y.-L. , Wang, S.-L., Lee, G.-H, S.-M. Peng and Rai-Shung Liu, J. Chem. Soc., Chem. Commun (1993) 1391.
51. Conjugated Addition of Organocopper Reagents to the enone group adjacent to a CpMo(CO)2(-allyl) Fragment. Lin, S. -H. , Lush, S. -F. , Cheng, W. -J. ; Lee, G. -H. , Peng, S. -M., Liao, Y. -L. , Wang, S. -L. and Liu, R. -S. , Organometallics, (1994) 13, 1711.
52. Mechanism of oxidation of Tungsten-1-2,5-dihydrofuranyl Compounds consecutively oxidized to 1-fur-2-yl and 1-3-butenolide compounds. Wang, S. -H. , Shiu, L. -H., Liao, Y. -L. , Wang, S. -L., Lee, G. -H., Peng, S. M. and Liu, R.-S., J. Am. Chem. Soc., (1994) 116, 5967.
53. Nucleophilic Addition on Tungsten-4-2-methoxycarbonyl-1,3-Pentadiene Cations: Control of Nucleophilic Regiochemistry by the Diene Conformations, M.-H Cheng, Y.-H Ho, G.-H Lee, S -M Peng, S.-M Peng, S.-Y Chu and R.-S Liu., Organometallics , (1994) 13, 4082.
54. Utilization of the CpMo(CO)2(3-2-COCH2C3H4] Enolate for stereoselective synthesis of 1R*, 3S*-4-pentene-1,3-diol, Liao, M, -F. ; Lee, G. -H.; Peng, S. M.; Liu, R. S. Organometallics, (1994), 14, 4973.
55. A Novel Tungsten-Mediated Carbonylation Reaction via a Tandem 1,3-Metal Sigmatropic Shift through a 1-Hex-2-en-4-yn-1-yl Group. K. W. Liang, G.-H. Lee, S. M. Peng and R. S. Liu, J. Chem. Soc. Chem. Commun., 1994, 2705.
56. Utilization of Molybdenum-allyl Compounds for Synthesis of -Methylene butyrolactones , S. H. Lin, W. J. Vong and R. S Liu. Organometallics, 1995, 14, 1619.
57. Stereochemical Course in Tungsten-Promoted Cyclocarbonylation Reactions to form five, six and seven-membered lactone ring. Chen C-C., J. S. Fan, G. H. Lee, S. M. Peng, S. L. Wang and R. S. Liu, J. Am. Chem. Soc. 1995, 117, 2933.
58. An Alkoxycarbonylation Reaction Involves a Tandem 1,3-Metal Shift Across Conjugated Allyl and alkyne Groups. K. W. Liang, G. H. Lee, S. M. Peng and R. S. Liu, 1995, Organometallics 14, 2353.
59. Tungsten-1-Five Membered Oxygenated Heterocycles Derived From Tungsten-1-Propargyl Compounds: Systematic Syntheses, Structural Rearrangement, Electrophilic Alkylations and Oxidative Demetalations, Wang, S. -H. , Shiu, L. -H., Liao, Y. -L. , Wang, S. -L., Lee, G. -H., Peng, S. M. and Liu, R.-S., J. Am. Chem. Soc.,1996, 118, 530.
60. Synthesis, Protonation and Electrophilic Alkylation of CpW(CO)2[3-2-(phenylethynyl)allyl] Complex, Chi-Yi Cheng, Chao-Hsieh Hsieh, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu., Organometallics, 1996, 15, 1565..
61. Tungsten-Promoted Intramolecular Annulation of Propargyl Bromides with Ketones and Aldehydes for Synthesis of Fused 2,5-Dihydrofurans, Shwu-Ju Shieh, Tze-Chin Tang, Jien-Shiu Lee, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, J. Org. Chem. 1996, 61, 3245.
62. Atypical Carbon-Carbon Bond Scisson and Deoxygenation Reaction in Protonation of Tungsten-1-oxabicyclic Compounds, Ling-Hung Shu, Hsin-Kuo Shiu, Da-Hsin Cheng, Sue-Lein Wang, and Rai-Shung Liu, J. Chem. Soc. Chem. Commun. 1996, 1041.
63. Tungsten-Promoted Intramolecular Alkoxycarbonylatrion for Syntheses of Complex Oxygenated Molecules. Chen Chi-Chung, Fan Jang-Shyang, Shieh, Su-Ju, Lee Gene-Hsian, Peng Shie-Ming, Wang Sue-Lang and Rai-Shung Liu, J. Am. Chem. Soc. 1996, 118, 9279..

64. Reaction of Tungsten-3-anti-Pentadienyl Compounds wth Reactive Olefins and Isocyanates: [5+2] Cycloaddition versus Acylation Reaction. Tesa-Chyi Yueh, Shie-Fu Lush, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, Organometallics, 1996, 15, 5669.

65. Tungsten-Promoted Constructions of Furan and Pyran Frameworks from Readily Available , -and-Alkynols: Tungsten(II)-Carbene Complex Can Function as Dicationic Synthon. Kwei-Wen Liang, Wen-Tai Li, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, J. Am. Chem. Soc. 1997, 119, 4404.

66. Tungsten-Mediated Syntheses of Fused -Methylene Butyrolactones From Propargyl Bromides Containing Tethered Aldehydes and Ketones, Shwu-Ju Shieh, Chi-Chun Cheng and Rai-Shung Liu, J. Org. Chem. 1997, 62, 1986.

67. Synthesis of bicyclic -Methylene Butyrolactones via intramolecular carbonylation of molybdenum-propargyl compounds. Shwu-Ju Shieh and Rai-Shung Liu, Tetrahedron Lett, 1997, 38, 5209.

68. Effects of silyl groups on the intramolecular cyclization of tungsten-alkynols: Formation of 2,5-dihydrofurans versus -lactones. Shwu-Ju Shieh, Fan Jang-Shyang and Rai-Shung Liu, Organometallics, 1997, 16, 3987..

69. Enantioselective syntheses of -methylene butyrolactones via asymmetric aminocarbonylation of tungsten-propargyl compounds, Lin-Hung Shiu, Sue-Lein Wang, Ming-Jung Wu and Rai-Shung Liu, J. Chem. Soc. Chem. Commun. 1997, 2005.

70. Acid-promoted isomerization of tungsten-1-2,5-dihydropyrrolyl complex to its tungsten-1-2,3-dihydropyrrolyl Isomer, Jang-Shyang Fan, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu Organometallics, 1997, 16, 4232



71. Transition-metal cation can undergo nucleophilic addition at the central carbon. Jang-Shyang Fan and Rai-Shung Liu, Organometallics, 1998, 17, 1002.
72. Palladium-catalyzed syntheses of oxygen- and nitrogen heterocycles via transmetalation of functionalized alkynyl stannanes. Shie-Tsung Chang, M.Chandrasekharam, Kwei-Wen Liang, Wen-Tai Li and Rai-Shung Liu, Tetrahedron Letter, 1998, 39, 643.
73. Synthesis of furopyridines via cycloaddition of unactivated nitriles with tungsten-substituted dienes. Wen-Tai Li, Fang-Chun Lai, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu, J. Am. Chem. Soc. 1998, 120, 4520.
74. Oxidative carbonylation of tungsten-alkynyl compounds via protonation with triflic Acid. Kwei-Wen Liang, M. Chandrasekharam, Chien-Le Li and Rai-Shung Liu, Organometallics 1998, 17, 2683.
75. Efficient synthesis of bicyclic lactones via tungsten-mediated intramolecular cycloalkenation reactions. Kwei-Wen Liang, M. Chandrasekharam, Chien-Le Li and Rai-Shung Liu, J. Org. Chem, 1998, 63, 7289.
76. An efficient way for total synthesis of Avenociolides and Isoavenociolides via tungsten--allyl compounds. Kesavaram Narkunan and Rai-Shung Liu, J. Chem. Soc. Chem. Commun. 1998, 1521.
77. Tungsten-alkynyl and propargyl compounds for organic syntheses. Liang K.-W.; Li Wen-Tai, M. Chandrasekharam and R. S. Liu, Applied and Pure Chemistry, 1998,, 1111.
78. Synthesis and ring cleavage of tungsten-1-oxabicycloheptene and 1-oxabicycloheptadiene compounds. Ling-Hun Shu, Hsin-Kuo Shiu, Da-Hsin Chen He-Long Hwang, Fen-Lin Liao, Sue-Lein Wang, and Rai-Shung Liu, Organometallics, 1998, 17, 4206.
79. Synthesis of -ethylene butyrolactones via tungsten--allyl complexes: total synthesis of methylene butyrolactones via tungsten--allyl complexes: total synthesis of (-)-Methylenolactocin. M. Chandrasekharam and Rai-Shung Liu, J. Org. Chem, 1998, 63, 9122..
80. Efficient total synthesis of natural Protolichesterinic acid and Rocellaric acid via tungsten--allyl complexes. Min-Jung Chen. and Rai-Shung Liu, Tetrahedron Lett, 1998, 9465.
81. Synthetic Application of Cyclopentadienyl Molybdenum and Tungsten Allyl and Diene Compounds in Organic Synthesis, In Advances in Metal-Organic Chemistry, L. S. Liebeskind Ed; JAI press: London, 1998, Vol 5, 145-187 (an invited review article).
82 Synthesis and Evaluation of [14C]-Labelled and Fluorescent-Tagged Paclitaxel Derivatives as New Biological Probes. Ch. S. Rao, Jao-Jia. Chu, Rai-Shung Liu. and Yiu-Kay Lai. Bioorganic & Medicianl Chemistry, 1998, 6, 2193.
83. A New Carbonylation Reaction of Tungsten-Propargyl Comppounds via Protonation at a Prolonged Period. Reniguntala J. Madhushaw, Gene-Hsian Lee, Shie-Ming Peng and Rai-Shung Liu. Organometallics, 1999, 18, 748.


  1. Intramolecular Cyclizations via Carbenoid Intermediates in Complexation of Alkynyltungsten Compounds with Co2(CO)8: A New Route to Pauson-Khand Reactions, Yun-Tai Shiu, Reniguntala J. Madhushaw, Wen-Tai Li, Yin-Chi Lin, Gene-Hsian Lee, Shie-Ming Penf, Fen-Lin Liao, Sue-Lein Wang and Rai-Shung Liu, J. Am. Chem. Soc. 1999, 121, 4066.




  1. Addition of Aromatic C-H Bonds to Terminal Metal-Carbonyl Groups. A New Method for Cyclocarbonylation of Aromatic Groups. Y.-R. Wu, G.-H. Lin; R. J. Madhushaw, K.-H. Horng, C.-C. Hu, C.-L. Li, F.-L. Liao, S.-L. Wang, R.-S. Liu, Organometallics, 1999, 18, 3566.




  1. Stereocontrolled Synthesis of Functionalized Bicyclic -Methylene Butyrolactones via Tungsten-Mediated Intramolecular Allylation of aldehydes. L.-H. Shiu, Y.-L. Li, C.-L. Li, C.-Y. Lao, W.-C. Chen, C.-Y. Yu, R.-S. Liu, J. Org. Chem.
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